English
[32] TBA, APEX reaction
Maciej Krzeszeski, Takehisa Maekawa, Hideto Ito, Kenichiro Itami
[31] TBA, APEX reaction
Kou P. Kawahara, Wataru Matsuoka, Hideto Ito, Kenichiro Itami
[30] An axially chiral 1,1′-biazulene and its π-extended derivative: synthesis, structures and properties
Chaolumen, Hideto Ito,* Kenichiro Itami*
Chem. Commun. 2019, 55, 9606-9609 . DOI: 10.1039/C9CC03510A【detail】
Selected as a front cover in volume 55, issume 65.
[29] Graphene Nanoribbon Dielectric Passivation Layers for Graphene Electronics
Nobuhiko Mitoma, Yuuta Yano, Hideto Ito,* Yuhei Miyauchi,* Kenichiro Itami*
ACS Appl. Nano Mater. 2019, in press. DOI: 10.1021/acsanm.9b00767【detail】
[28] Living annulative π-extension polymerization for graphene nanoribbon synthesis
Yuuta Yano, Nobuhiko Mitoma,Kaho Matsushima, Feijiu Wang, Yusuke Matsui, Akira Takakura, Yuhei Miyauchi, Hideto Ito,* Kenichiro Itami*
Nature, 2019, 571, 387–392. DOI: 10.1038/s41586-019-1331-z【detail】
press release (JP), press release (En)
Highlighted by NHK、中日新聞20190627、日刊工業新聞20190627、毎日新聞20190711、読売新聞20190630、科学新聞20190705
[27] Bay-region Selective Annotative π-Extension (APEX) of Perylene Diimides with Arynes
Takayuki Nakamuro, Kazushi Kumazawa, Hideto Ito,* Kenichiro Itami*
Synlett, 2019, 30, 423–428. DOI: 10.1055/s-0037-1611668.
[26] Discovery of Plant Growth Stimulants by C–H Arylation of 2-Azahypoxanthine
Hiroyuki Kitano, Jae-Hoon Choi, Ayaka Ueda, Hideto Ito , Shinya Hagihara, Toshiyuki Kan , Hirokazu Kawagishi , and Kenichiro Itami
Org. Lett. 2018, 20, 5684–5687. DOI: 10.1021/acs.orglett.8b02407 【detail】
Highlighted in C&EN News
[25] Annulative π-Extension of Indoles and Pyrroles with Diiodobiaryls by Pd Catalysis: Rapid Synthesis of Nitrogen-Containing Polycyclic Aromatic Compounds
Hiroyuki Kitano, Wataru Matsuoka, Hideto Ito,* Kenichiro Itami*
Chem. Sci.2018, 9, 7556-7561. DOI: 10.1039/c8sc02802h 【detail】
[24] Palladium-Catalyzed Esterification of Carboxylic Acids with Aryl Iodides
Hiroyuki Kitano, Hideto Ito,* Kenichiro Itami*
Org. Lett.2018, 20, 2428–2432. DOI: 10.1021/acs.orglett.8b00775 【detail】
Highlighted as Most read articles (7th May, 2018)
[23] C-H Arylation of Phenanthrene with Trimethylphenylsilane by Pd/o-Chloranil Catalysis: Computational Studies on the Mechanism, Regioselectivity, and Role of o-Chloranil
Mari Shibata, Hideto Ito,* Kenichiro Itami*
J. Am. Chem. Soc. 2018, 140, 2196–2205. DOI: 10.1021/jacs.7b11260【detail】
[22] Oxidative Homocoupling Reaction of Aryltrimethylsilanes by Pd/o-chloranil Catalysis
Mari Shibata, Hideto Ito,* Kenichiro Itami*
Chem. Lett.2017, 46, 1701–1704. DOI: 10.1246/cl.170723.【detail】
[21] Rapid Access to Nanographenes and Fused Heteroaromatics by Palladium-Catalyzed Annulative π-Extension Reaction of Unfunctionalized Aromatics with Diiodobiaryls
Wataru Matsuoka, Hideto Ito,* Kenichiro Itami*
Angew. Chem. Int. Ed. 2017, 56, in press. DOI:
[20] Annulative π-Extension (APEX) of Heteroarenes with Dibenzosiloles and Dibenzogermoles by Palladium/o-Chloranil Catalysis
Kyohei Ozaki, Wataru Matsuoka, Hideto Ito,* Kenichiro Itami*
Org. Lett., 2017, 19, 1930–1933. DOI: 10.1021/acs.orglett.7b00684【detail】
[19] One-Step Annulative p-Extension of Alkynes with Dibenzosiloles Dibenzogermoles by Palladium/o-chloranil Catalysis
Kyohei Ozaki, Keiichiro Murai, Wataru Matsuoka, Katsuaki Kawasumi, Hideto Ito,* and Kenichiro Itami*
Angew. Chem. Int. Ed. 2017, 56, 1362–1364. DOI: 10.1002/ange.201610374 【detail】
Selected as a Hot Paper
Highlighted in Synfacts
[18] Key Structural Elements of Unsymmetrical Cyanine Dyes for Highly Sensitive Fluorescence Turn-on DNA Probe
Kakishi Uno, Taeko Sasaki, Nagisa Sugimoto, Hideto Ito, Taishi Nishihara, Shinya Hagihara, Tetsuya Higashiyama, Narie Sasaki, Yoshikatsu Sato and Kenichiro Itami*
Chem. Asian J. 2016, accepted. DOI: 10.1002/asia.201601430【detail】
[17]Construction of Covalent Organic Nanotubes by Light-Induced Cross-Linking of Diacetylene-Based Helical Polymers
Kaho Maeda, Liu Hong, Taishi Nishihara, Yusuke Nakanishi, Yuhei Miyauchi, Ryo Kitaura, Naoki Ousaka, Eiji Yashima, Hideto Ito,* and Kenichiro Itami*
J. Am. Chem. Soc. 2016, 138, 11001–11008. DOI: 10.1021/jacs.6b05582 【detail】【press release (JP)】[press release(EN)]
Selected as the cover art in J. Am. Chem. Soc. 2016, vol.138, issue 38
Highlighted in JACS SPOTLIGHTS (J. Am. Chem. Soc. 2016, 138, 10717. DOI: 10.1021/jacs.6b08657)
Most Read Article Article (Total 2343 views: accessed in 5th, Sep., 2016)
Highlighted in ChemStation Spotlight Research
Highlighted in News Paper: 日経産業新聞20160809、中日新聞20160901, 科学新聞20160906
Other highlights
[Web News in Japanese]: マイナビニュース、gunosy、excitedニュース、J-Net21、livedoor、E-start注目記事、日経テクノロジーオンライン、EE Times Japan、Yahoo ニュース、Busicom Post、fabcross for エンジニア、Security Online News、2channel News Navigator、はてなブックマーク、ジョルダンニュース!、ニコニコニュース、gooニュース、NTTドコモ、Mapion、Infoseek、Biglobeニュース、日経プレスリリース、
[Web News in English]: Health Medicine Network, Science Newsline, Physorg.com, ScienceDaily, nanowerk, AlphaGalileo, ResearchSEA, EurekAlert, Space Daily, Scicasts, Nanotechnology Now, Chem Europe,
[Web News in Russian]: RAMBLER NEWS SERVICE,
[Web News in Chinese]: 权威国防科技信息门户,
[16] Macrocyclization by Rh-Catalyzed Cross-Cyclotrimerization of L-Shaped Diynes with Di-tert-butyl Acetylenedicarboxylate: Effect of Bent Linkers of Diynes
S. Nishigaki, Y. Miyauchi, K. Noguchi, H. Ito, K. Itami, Y. Shibata, K. Tanaka*
Eur. J. Org. Chem. 2016, in press. DOI: 10.1002/ejoc.201600909【detail】
[15] Helically Twisted Tetracene: Synthesis, Crystal Structure, and Photophysical Properties of Hexabenzo[a,c,fg,j,l,op]tetracene
Yuuta Yano, Hideto Ito, Yasutomo Segawa, and Kenichiro Itami
Synlett, 2016, 27, 2081-2084. DOI: 10.1055/s-0035-1561455 【detail】
[14]. A Theoretical Study on the Strain Energy of Carbon Nanobelts
Yasutomo Segawa, Akiko Yagi, Hideto Ito, and Kenichiro Itami
Org. Lett. 2016, 18, 1430–1433. DOI: 10.1021/acs.orglett.6b00365 【detail】
[13]. Pyridylidene ligand facilitates gold-catalyzed oxidative C–H arylation of heterocycles
Kazuhiro Hata, Hideto Ito, Yasutomo Segawa and Kenichiro Itami
Beilstein J. Org. Chem. 2015, 11, 2737. DOI: 10.3762/bjoc.11.295
[12].Concise Synthesis and Facile Nanotube Assembly of a Symmetrically Multi-Functionalized Cycloparaphenylene
Yuta Miyauchi, Shintaro Fujii, Kohei Johmoto, Nobuhiro Yasuda, Hideto Ito, Kenichiro Itami, Hidehiro Uekusa, Manabu Kiguchi, and Ken Tanaka
Chem. Eur. J. 2015, in press. DOI: 10.1002/chem.201504185.
selected as Hot Paper
[11]. One-shot K-region-selective Annulative π-Extension for Nanographene Synthesis and Functionalization
Kyohei Ozaki, Katsuaki Kawasumi, Mari Shibata, Hideto Ito, and Kenichiro Itami
Nature Commun. 2015, 6:6251. DOI: 10.1038/ncomms7251.【detail】
Highlighted in News Papers (Chunichi Shinbun, Nikkan Kogyo Shimbun, Zaikeishinbun)
Highlighted in Science Portal, Scicasts, Phys Org, AZO NANO, nano werk, Science Daily, Asia Research News, Eurek Alert.
[10]. Thiophene-Based, Radial π-Conjugation: Synthesis, Structure, and Photophysical Properties of Cyclo-1,4-phenylene-2’,5’-thienylenes
Hideto Ito, Yukari Mitamura, Yasutomo Segawa and Kenichiro Itami
Angew. Chem. Int. Ed. 2015, 54, 159-163. DOI: 10.1002/anie.201409389【detail】
Selected as a inside cover picture in issue 1, 2015.
Highlighted in Synfacts 2015, 11,141.
[9]. One-shot Indole-to-Carbazole π-Extension by Pd-Cu-Ag Trimetallic System
Kyohei Ozaki, Hua Zhang, Hideto Ito, Aiwen Lei and Kenichiro Itami
Chem. Sci. 2013, 4, 3416–3420, DOI: 10.1039/C3SC51447A 【detail】
Most Read Articles in June and July in 2013
Selected as “HOT Chem Sci articles for June” in 2013
Selected as Back Cover in issue 9, 2013
Highlighted in Synfacts
Selected as “Top 25 most-read Chemical Science articles in 2013”
[8]. Construction of Eight-Membered Carbocycles through Gold Catalysis with Acetylene-Tethered Silyl Enol Ethers
Tomohiro Iwai, Hiori Okochi, Hideto Ito and Masaya Sawamura
Angew, Chem. Int. Ed., 2013, 52, 4239–4242. DOI: 10.1002/anie.201300265
[7]. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters
Hideto Ito, Ayumi Harada, Hirohisa Ohmiya, Masaya Sawamura
Adv. Synth. Catal., 2013, 355, 647–652. DOI: 10.1002/adsc.201200949
[6]. Formation of Quaternary Carbon Centers via Highly Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group
Yusuke Ueki, Hideto Ito, Ippei Usui, Bernhard Breit
Chem. Eur. J., 2011, 17, 8555–8558. DOI: 10.1002/chem.201101186
[5]. Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold–Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo–dig Cyclization
Hideto Ito, Tomoya Harada, Hirohisa Ohmiya, Masaya Sawamura
Beilstein J. Org. Chem., invited paper, 2011, 7, 951-959. DOI: 10.3762/bjoc.7.106
[4]. Construction of Methylenecycloheptane Frameworks through 7-Exo–Dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine–Gold Complex
Hideto Ito, Hirohisa Ohmiya, Masaya Sawamura
Org. Lett. 2010, 12, 4380–4383. DOI: 10.1021/ol101860j
[3]. General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate
Hirohisa Ohmiya, Hideto Ito, and Masaya Sawamura
Org. Lett. 2009, 11, 5618–5620. DOI: 10.1021/ol902339a
[2]. Cyclization of Non-Terminal Alkynic b-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand
Hideto Ito, Yusuke Makida, Atsuko Ochida, Hirohisa Ohmiya, Masaya Sawamura
Org. Lett. 2008, 10, 5051–5054. DOI: 10.1021/ol802079r
[1]. Using Triethynylphosphine Ligands Bearing Bulky End Caps to Create a Holey Catalytic Environment: Application to Gold(I)-Catalyzed Alkyne Cyclizations
Atsuko Ochida, Hideto Ito, Masaya Sawamura
J. Am. Chem. Soc, 2006, 128, 16486-16487. DOI: 10.1021/ja066800c
【Reviews】
[5] Polycyclic Arene Synthesis by Annulative π-Extension
Hideto Ito, Yasutomo Segawa, Kei Murakami, Kenichiro Itami*
J. Am. Chem. Soc. 2019, 141, 3-10.
DOI: 10.1021/jacs.8b09232 【detail】
[4] Recent advances in acetylene-based helical oligomers and polymers: Synthesis, structures, and properties
Michihisa Toya, Hideto Ito* and Kenichiro Itami*
Tetrahedron Lett (digest paper), 2018, 59, 1531–1547. DOI: 10.1016/j.tetlet.2018.03.018 【detail】
[3] Annulative π-Extension (APEX): An Enabling Reaction for Rapid Access to Fused Aromatics, Heteroaromatics, and Nanographenes
Hideto Ito,* Kyohei Ozaki, and Kenichiro Itami*
Angew. Chem. Int. Ed.2017, 56, 11144–11164. DOI: 10.1002/anie.201701058.【detail】
[2]. Structurally Uniform and Atomically Precise Carbon Nanostructures
Yasutomo Segawa, Hideto Ito, and Kenichiro Itami
Nature Rev. Mater. 2016, 1, 15002.（創刊号）DOI: 10.1038/natrevmats.2015.2 [detail]
highlighted in natureasia.com
[1]. Oxidative Cross-Coupling Reaction by Gold/Selectfluor® Catalysis
Hideto Ito
Journal of Synthetic Organic Chemistry, Japan, 2013, 76, 1075–1076. DOI: 10.5059/yukigoseikyokaishi.71.1075
【Books】
[2]. 理系基礎化学実験、第１版、第９冊、第10冊
村田静昭、浦野扶美、吉村正宏、伊藤英人 共著、2015年2月、2016年2月、学術図書出版、ISBN: 978-4-7806-0143-5
[1]. Cross-Dehydrogenative-Coupling Reactions without Metals
Hideto Ito, Kirika Ueda, and Kenichiro Itami
From C-H to C-C Bonds : Cross-Dehydrogenative-Coupling (Eds: Chao-Jun Li, DOI: 10.1039/9781782620082), Chapter 8,
Royal Society of Chemistry, 2015, 153–196. DOI: 10.1039/9781782620082-00153.
