2012

2012

(154) Excited States in Cycloparaphenylenes: Dependence of Optical Properties on Ring Length

Taishi Nishihara, Yasutomo Segawa, Kenichiro Itami, and Yoshihiko Kanemitsu

J. Phys. Chem. Lett. 20123, 1325-3128. DOI: 10.1021/jz3014826 【detail

(153) Palladium-Catalyzed C–H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation

Qianyan Zhang, Katsuaki Kawasumi, Yasutomo Segawa, Kenichiro Itami, and Lawrence T. Scott

J. Am. Chem. Soc. 2012, 134, 15664–15667. DOI: 10.1021/ja306992k 【detail

Highlighted in Computational Chemistry Highlights

Most Read Article in September 2012

(152) Palladium-catalyzed tetraallylation of C60 with allyl chloride and allylstannane: Mechanism, regioselectivity, and enantioselectivity

Masakazu Nambo, Atsushi Wakamiya, and Kenichiro Itami

Chem. Sci. 20123, 3474-3481. DOI: 10.1039/C2SC21126B 【detail

(151) Synthesis and Properties of All-Benzene Carbon Nanocages: A Junction Unit of Branched Carbon Nanotubes

Katsuma Matsui, Yasutomo Segawa, Tomotaka Namikawa, Kenji Kamada, and Kenichiro Itami

Chem. Sci. 20134, 84-88. DOI: 10.1039/C2SC21322B 【detail

Highlighted in Newspapers (Yomiuri ShinbunChunichi Shinbun, JIJI Press, Yahoo! NewsThe Chemical Daily, Tokyo Shinbun, Kagaku Shinbun)

Highlighted in Chemistry WorldC&ENNewtonSYNFACTS

Most Read Articles in August and September 2012

Selected as Inside Back Cover

(150) Pd-catalyzed direct C-H bond functionalization of spirocyclic sigma-1 ligands: generation of a pharmacophore model and analysis of reverse binding mode by docking into a 3D homology model of the sigma-1 receptor

Christina Meyer, Dirk Schepmann, Shuichi Yanagisawa, Junichiro Yamaguchi, Valentina Dal Col, Erik Laurini, Kenichiro Itami, Sabrina Pricl, and Bernhard Wünsch

J. Med. Chem. 201255, 8047. DOI: 10.1021/jm300894h 【detail

(149) Late-Stage C-H Bond Arylation of Spirocyclic s1 Ligands for Analysis of Complementary s1 Receptor Surface

Christina Meyer, Dirk Schepmann, Shuichi Yanagisawa, Junichiro Yamaguchi, Bernhard Wünsch, and Kenichiro Itami

Eur. J. Org. Chem. 2012, 5972–5979. DOI: 10.1002/ejoc.201200837 【detail

(148) Recent Progress in Nickel-Catalyzed Biaryl Coupling

Junichiro Yamaguchi, Kei Muto, and Kenichiro Itami

Eur. J. Org. Chem. 20132013, 19-30. DOI: 10.1002/ejoc.201200914 【detail

(147) Synthesis of Bioactive Compounds through C-H Bond Functionalization

Junichiro Yamaguchi and Kenichiro Itami

Fine Chemicals 201241, 38.

(146) Chemical Synthesis of Nanographenes

Katsuaki Kawasumi and Kenichiro Itami

Function and Applications of Graphenes 2 2012, in press.

(145) Direct C-H Arylation of Polycyclic Aromatic Hydrocarbons toward Bottom-up Synthesis of Graphene

Yasutomo Segawa and Kenichiro Itami

Catalysts and Catalysis 201254, 409-413. 【detail

(144) Biaryl Synthesis through Metal-Catalyzed C-H Arylation

Junichiro Yamaguchi and Kenichiro Itami

Metal Catalyzed Cross-Coupling Reactions and More; Wiley-VCH, in press.

(143) C-H Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

Junichiro Yamaguchi, Atsushi D. Yamaguchi, and Kenichiro Itami

Angew. Chem. Int. Ed. 201251, 8960–9009. 10.1002/anie.201201666 【detail

Selected as the Cover of the Issue.
Highlighted in Chemistry Views.

(142) Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A

Kazuma Amaike, Kei Muto, Junichiro Yamaguchi, and Kenichiro Itami,

J. Am. Chem. Soc. 2012134, 13573–13576. DOI: 10.1021/ja306062c 【detail

Highlighted in Newspapers (Chu-nichiAsahi, The Chemical DailyYahoo!News, Mynavi-News, Nikkan kogyoKagaku Shinbun)

Most Read Articles in August 2012

(141) Pd- and Cu-catalyzed C–H Arylation of Indazoles

Keika Hattori, Kazuya Yamaguchi, Junichiro Yamaguchi and Kenichiro Itami

Tetrahedron (Special Issue)201268, 7605-7612. DOI: 10.1016/j.tet.2012.05.091

(140) 1,3,5-Triaryl 2-Pyridylidene: Base-Promoted Generation and Complexation

Kazuhiro Hata, Yasutomo Segawa, and Kenichiro Itami

Chem. Commun. 201248, 6642–6644. DOI: 10.1039/C2CC33184E 【detail

(139) Carbon Nanoring: A Shortest Carbon Nanotube

Yasutomo Segawa and Kenichiro Itami

Expected Materials for the Future201212, 10-15. linkdetail

(138) Size-selective synthesis of [9]-[11] and [13]cycloparaphenylenes

Yuuki Ishii, Yusuke Nakanishi, Haruka Omachi, Sanae Matsuura, Katsuma Matsui, Hisanori Shinohara, Yasutomo Segawa, and Kenichiro Itami

Chem. Sci. 20123, 2340-2345. DOI: 10.1039/C2SC20343J 【detail

Highlighted in RSC Chemical Science Blog
Top ten most accessed articles in May 2012

(137) Synthesis of Cycloparaphenylenes and Related Carbon Nanorings: A Step toward the Controlled Synthesis of Carbon Nanotubes

Haruka Omachi, Yasutomo Segawa, and Kenichiro Itami

Acc. Chem. Res. 201245, 1378-1389. DOI: 10.1021/ar300055x 【detail

Most Read Articles in May 2012
Selected as the Cover in the Issue of August 2012

(136) Hindered Biaryls by C-H Coupling: Bisoxazoline-Pd Catalysis Leading to Enantioselective C-H Coupling

Kazuya Yamaguchi, Junichiro Yamaguchi, Armido Studer, and Kenichiro Itami

Chem. Sci, 20123, 2165-2169. DOI:10.1039/C2SC20277Hdetails

Highlighted in RSC Chemical Science blog
Most Read Articles in March and April 2012

(135) Synthesis and Properties of Cycloparaphenylene-2,5-pyridylidene: A Nitrogen-Containing Carbon Nanoring

Katsuma Matsui, Yasutomo Segawa, and Kenichiro Itami

Org. Lett. 201214, 1888-1891. DOI: 10.1021/ol3005112 【details

(134) Combined Experimental and Theoretical Studies on the Photophysical Properties of Cycloparaphenylenes

Yasutomo Segawa, Aiko Fukazawa, Sanae Matsuura, Haruka Omachi, Shigehiro Yamaguchi, Stephan Irle, and Kenichiro Itami

Org. Biomol. Chem. 2012, 10, 5979-5984. DOI: 10.1039/C2OB25199J 【details

(133) Synthesis and Properties of [9]Cyclo-1,4-naphthylene: A pi-Extended Carbon Nanoring

Akiko Yagi, Yasutomo Segawa, and Kenichiro Itami

J. Am. Chem. Soc. 2012134, 2962–2965. DOI: 10.1021/ja300001g 【detail

Most Read Articles (February, 2012)
Highlighted in Computational Organic Chemistry

Highlighted in JACS Image Challenge (JACSß)

(132) Toward Controlled Synthesis of Carbon Nanotubes and Graphene

Kenichiro Itami

Pure Appl. Chem. 201284, 907-916. DOI: 10.1351/PAC-CON-11-11-15s【detail

(131) Mechanistic Studies on the Pd-catalyzed Direct C-H Arylation of 2-Substituted Thiophene Derivatives with Arylpalladium Bipyridyl Complexes

Marc Steinmetz, Kirika Ueda, Stefan Grimme, Junichiro Yamaguchi, Sylvia Kirchberg, Kenichiro Itami, and Armido Studer

Chem. Asian J. 201271256-1260. DOI: 10.1002/asia.201101011 【detail

(130) The 1,1-Carboboration of Bis(alkynyl)phosphines as a Route to Phosphole Compounds

Juri Möbus, Quentin Bonnin, Kirika Ueda, Roland Fröhlich, Kenichiro Itami, Gerald Kehr, and Gerhard Erker

Angew. Chem. Int. Ed201251, 1954-1957. DOI: 10.1002/anie.201107398 【details

(129) CPP: A Beautiful Benzene-Based Ring Molecule

Kenichiro Itami

Chemistry & Chemical Industry 201265, 115-116.

(128) Pd(OAc)2/o-Chloranil/M(OTf)n: A Catalyst for the Direct C–H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl-, Silyl-, and Unfunctionalized Arenes

Katsuaki Kawasumi, Kenji Mochida, Tomonori Kajino, Yasutomo Segawa, and Kenichiro Itami

Org. Lett. 201214, 418–421. DOI: 10.1021/ol203235w 【details

(127) Nickel-Catalyzed C−H/C−O Coupling of Azoles with Phenol Derivatives

Kei Muto, Junichiro Yamaguchi, Kenichiro Itami,

J. Am. Chem. Soc. 2012134, 169-172. DOI: 10.1021/ja210249h 【details

Highlighted in Newspapers (YomiuriChu-nichiThe Chemical DailyYahoo!News, NanotechJapan Nikkan kogyoKagaku Shinbun), Most Read Articles (January, 2012), Highlighted as a “SynStory” article in SYNFORM (April 2012), Highlighted in Chemical Engineering (Feb 2012)

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