Blog

Selective Synthesis of [12]Cycloparaphenylene

Hiroko Takaba, Haruka Omachi, Yosuke Yamamoto, Jean Bouffard, Kenichiro Itami, Angew. Chem. Int. Ed, 2009, ASAP
DOI: 10.1002/anie.200902617

 

Tighten your belt:

[12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane-1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization.

Related post

  1. Chemical hijacking of auxin sign…
  2. A Modular and Size-Selective Syn…
  3. Flexible Reaction Pocket on Bulk…
  4. Exciton Recombination Dynamics i…
  5. Late-Stage C-H Bond Arylation of…
  6. Theoretical Studies on the Struc…
  7. Decarbonylative C–H Coupling of …
  8. (日本語) Direct Coupling of Naphtha…

Comment

  • Trackback are closed

  • Comments (0)

  1. No comments yet.

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP