Blog

Aziridinofullerene: A Versatile Platform for Functionalized Fullerenes

Masakazu Nambo, Yasutomo Segawa, and Kenichiro Itami

J. Am. Chem. Soc. 2011, ASAP. DOI: 10.1021/ja111213k

 

Controlled Synthesis of a Range of Functionalized Fullerenes

An aziridine moiety on the fullerene core can serve as an acid-triggered reacting template for the controlled synthesis of a range of functionalized fullerenes that are otherwise difficult to synthesize in an efficient and selective manner. A copper-catalyzed aziridination of C60 for the practical synthesis of aziridinofullerene and acid-catalyzed reactions of aziridinofullerene with mono- and bifunctional nucleophiles as well as alkynes are described. The rapid generation of structural diversity in a single chemical operation using the common platform is notable.

 

Related post

  1. (日本語) test
  2. Phenanthro[9,10-a]corannulene by…
  3. Pd(OAc)2/o-Chloranil/M(OTf)n: A …
  4. Structurally uniform and atomica…
  5. Theoretical Elucidation of Poten…
  6. One-Step Annulative π-Extension …
  7. Construction of Heptagon‐Contain…
  8. Synthesis of Bioactive Compounds…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP