Blog

Synthesis and Properties of Methylene-bridged [6]Cyclo-2,6-naphthylene

Synthesis and Properties of Methylene-bridged [6]Cyclo-2,6-naphthylene

Nobushige Kai, Hideya Kono, Akiko Yagi, Kenichiro Itami, Synlett 2022, accepted. DOI: 10.1055/a-2009-8219

The synthesis of a novel structurally constrained nanobelt, methylene-bridged [6]cyclo-2,6-naphthylene ([6]MCN), has been achieved by nickel-mediated intramolecular aryl–aryl coupling of triflated prism[6]arene. The structural and electronic properties of [6]MCN were revealed through NMR study and photophysical measurements. In contrast to methylene-bridged [6]cycloparaphenylene ([6]MCPP), our previously synthesized benzene-based analogue, [6]MCN has low strain energy (77.4 kcal·mol–1) and bright fluorescence (Φ = 0.20)

Related post

  1. Phenanthro[9,10-a]corannulene by…
  2. Synthesis of Polybenzoacenes: An…
  3. Six-fold C–H Borylation of Hexa-…
  4. カーボンナノリング:最短のカーボンナノチューブ
  5. Synthesis of Cycloiptycenes from…
  6. Selective Introduction of Organi…
  7. Synthesis and Dimerization of Ch…
  8. Curved Oligophenylenes as Donors…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP