Blog

Palladium-Catalyzed C-H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation

Qianyan Zhang, Katsuaki Kawasumi, Yasutomo Segawa, Kenichiro Itami, Lawrence T. Scott

J. Am. Chem. Soc. 2012, ASAP. DOI: 10.1021/ja306992k


All ten C–H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C–H activation. To relieve congestion among the ten tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.

Related post

  1. Palladium-catalyzed tetraallylat…
  2. Late-Stage C-H Bond Arylation of…
  3. Perfluorocycloparaphenylenes
  4. Palladium-free synthesis of [10]…
  5. Palladium-Catalyzed Esterificati…
  6. Palladium-Catalyzed C–H and C–N …
  7. C−H Bond Functionalization: Emer…
  8. Selective Synthesis of [12]Cyclo…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP