Recent Publication

Nickel-Catalyzed C-H Arylation of Azoles with Haloarenes: Scope, Mechanism, and Applications to the Synthesis of Bioactive Molecules

Takuya Yamamoto, Kei Muto, Masato Komiyama, Jerôme Canivet, Junichiro Yamaguchi, and Kenichiro Itami*

Chem. Eur. J2011, Early View

DOI: 10.1002/chem.201101091

New couples:

Novel Ni-based catalytic systems for the -H arylation of azoles with haloarenes have been developed (see scheme). Mechanistic studies as well as applications to the synthesis of biologically active com- pounds (febuxostat, tafamidis, and texaline) are also described.

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