Blog

Aromatic C–H Coupling with Hindered Arylboronic Acids by Pd/Fe Dual Catalysts

Kazuya Yamaguchi, Hiroki Kondo, Junichiro Yamaguchi, and Kenichiro Itami

Chem. Sci. 2013, Accepted Manuscript. DOI: 10.1039/C3SC51206A

 

Pd/Fe dual catalysts for C–H coupling

An aerobic oxidative coupling of arenes/alkenes with arylboronic acids (C–H/C–B coupling) using catalytic Pd(II)/sulfoxide–oxazoline (sox) ligand and iron-phthalocyanine (FePc) has been developed. This dual catalyst system enables the synthesis of sterically hindered heterobiaryls and styrene derivatives under air without stoichiometric co-oxidants. Additionally, this chemistry demonstrated toward an enantioselective biaryl coupling through C–H functionalization.

Related post

  1. Six-fold C–H Borylation of Hexa-…
  2. Theoretical Elucidation of Poten…
  3. Synthesis and characterization o…
  4. Electro-Activated Conductivity a…
  5. Toward Controlled Synthesis of C…
  6. Perfluorocycloparaphenylenes: Fu…
  7. Synthesis of Natural Products an…
  8. Manganese-Catalyzed Intermolecul…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP