Blog

The 1,1-Carboboration of Bis(alkynyl)phosphines as a Route to Phosphole Compounds

Juri Möbus, Quentin Bonnin, Kirika Ueda, Roland Fröhlich, Kenichiro Itami, Gerald Kehr, and Gerhard Erker

Angew. Chem. Int. Ed. Early View. DOI: 10.1002/anie.201107398

 

B(C6F5)3 efficiently con- verts a series of bis(alkynyl)phosphines into highly substituted 3-borylphospholes through a twofold 1,1-carboboration reaction sequence. The boron substituted phospholes were also used as substrates in Suzuki–Miyaura type cross-coupling reactions (see scheme).

Related post

  1. A Quest for Structurally Uniform…
  2. Oxidative Biaryl Coupling of Thi…
  3. Synthesis of Open-Shell Ladder π…
  4. Cycloparaphenylene-Based Ionic D…
  5. Oxidative Homocoupling Reaction …
  6. Regiodivergent Cross-Dehydrogena…
  7. Palladium-Catalyzed Esterificati…
  8. Synthesis and properties of all-…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP