Blog

Heteroatom-Embedding Annulative π-Extension (Hetero-APEX) Reactions – An Overview

Heteroatom-Embedding Annulative π-Extension (Hetero-APEX) Reactions – An Overview
Hideto Ito,* Kou. P. Kawahara, Kenichiro Itami*
Synthesis, in press. DOI: 10.1055/a-2169-4078

Heteroatom-embedded polycyclic aromatic compounds (hetero-PACs) are a class of organic compounds contributing to a variety of research fields such as materials science, chemical biology and so on. For applications using hetero-PACs, efficient preparation of hetero-PACs is essential. In particular, reactions transforming unfunctionalized aromatic compounds to hetero-PACs using appropriate heteroatom-containing aromatic compounds (π-extending agents) represent the most ideal way to prepare hetero-PACs. In this review, such heteroatom-embedding annulative π-extension (hetero-APEX) reactions including their reaction mechanisms and scope of substrates are described.

Related post

  1. Manganese-Catalyzed Intermolecul…
  2. Synthesis and Structure of a Pro…
  3. Synthesis of Octaaryl Naphthalen…
  4. N-doped Nonalternant Aromatic Be…
  5. Nickel-Catalyzed Aromatic C–H Fu…
  6. One-shot Indole-to-Carbazole π-E…
  7. Toward Controlled Synthesis of C…
  8. Synthesis of Heptagon-Containing…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP