Blog

Aromatic C–H Borylation by Nickel Catalysis

Hua Zhang, Shinya Hagihara, and Kenichiro Itami

Chem. Lett. 2015, ASAP. DOI: 10.1246/cl.150154


The first nickel-catalyzed aromatic C–H borylation is described. In the presence of catalytic amounts of Ni(cod)2, tricyclopentylphosphine, and CsF, benzene and indole derivatives can be borylated with B2pin2. The N-heterocyclic carbene IPr was also found to be an effective ligand. The kinetic isotope effect experiments showed that C–H cleavage is likely involved in the rate-determining step.

Related post

  1. Programmed Synthesis of Arylthia…
  2. Palladium-catalyzed tetraallylat…
  3. 1,3,5-Triaryl 2-Pyridylidene: Ba…
  4. Synthesis of a zigzag carbon nan…
  5. Regiodivergent Cross-Dehydrogena…
  6. Bare aromatic polymers synthesiz…
  7. Reversible modulation of circadi…
  8. Synthesis and properties of all-…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP