Blog

Pyridine-Based Dicarbene Ligand: Synthesis and Structure of Bis-2-pyridylidene Palladium Complex

Tetsushi Yoshidomi, Yasutomo Segawa, and Kenichiro Itami
Chem. Commun. 2013, Accepted Manuscript. DOI: 10.1039/C3CC42655F


We herein report the synthesis of a bis-2-pyridylidene palladium(II) complex as an isoelectronic structure of the well-known 2,2′-bipyridine complexes. One-pot or stepwise C–Cl oxidative addition followed by base-mediated C–H palladation of the chlorobipyridine dication to palladium(0) yielded the bis-2-pyridylidene palladium(II) carbonate smoothly.

 

Related post

  1. Casein kinase 1 family regulates…
  2. Nickel-Catalyzed Biaryl Coupling…
  3. Infinitene: A Helically Twisted …
  4. Synthesis and Properties of [9]C…
  5. Synthesis and characterization o…
  6. Synthesis of Polybenzoacenes: An…
  7. Corannulene–Helicene Hybrids: Ch…
  8. Thiophene-Fused π-Systems from D…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP