Blog

CH Alkenylation of Azoles with Enols and Esters by Nickel Catalysis

 

Lingkui Meng, Yuko Kamada, Kei Muto, Junichiro Yamaguchi, Kenichiro Itami,

Angew. Chem. Int. Ed. 2013, Early View. DOI:10.1002/anie.201304492

Rather u(Ni)que: Two new C[BOND]H alkenylation reactions, that is C[BOND]H/C[BOND]O alkenylation and decarbonylative C[BOND]H alkenylation, of azoles are uniquely catalyzed by Ni/dcype. These azole alkenylation reactions are successfully applied to the convergent formal synthesis siphonazole B.

 

 

Related post

  1. Molecular Catalysis for Fulleren…
  2. Palladium-Catalyzed Esterificati…
  3. Functionalization of a Simple Di…
  4. Adamantane-annulated arenes
  5. Synthesis of Bioactive Compounds…
  6. Synthesis and Properties of [9]C…
  7. Reversible modulation of circadi…
  8. Aromatic C–H Coupling with Hinde…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP