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Lingkui Meng, Yuko Kamada, Kei Muto, Junichiro Yamaguchi, Kenichiro Itami,
Angew. Chem. Int. Ed. 2013, Early View. DOI:10.1002/anie.201304492
Rather u(Ni)que: Two new CH alkenylation reactions, that is C
H/C
O alkenylation and decarbonylative C
H alkenylation, of azoles are uniquely catalyzed by Ni/dcype. These azole alkenylation reactions are successfully applied to the convergent formal synthesis siphonazole B.