Blog

Palladium-Catalyzed C-H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation

Qianyan Zhang, Katsuaki Kawasumi, Yasutomo Segawa, Kenichiro Itami, Lawrence T. Scott

J. Am. Chem. Soc. 2012, ASAP. DOI: 10.1021/ja306992k


All ten C–H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C–H activation. To relieve congestion among the ten tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.

Related post

  1. Selective Transformation of Stry…
  2. Toward Controlled Synthesis of C…
  3. Regioselective Unsymmetrical Tet…
  4. Manganese-Catalyzed Intermolecul…
  5. Ni-Catalyzed α-Arylation of Este…
  6. Initiation of carbon nanotube gr…
  7. A Modular and Size-Selective Syn…
  8. Structurally uniform and atomica…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP