Blog

Selective Synthesis of [7]- and [8]Cycloparaphenylenes

Friederike Sibbel, Katsuma Matsui, Yasutomo Segawa, Armido Studer and Kenichiro Itami

Chem. Commun. 2013, Accepted Manuscript, doi: 10.1039/C3CC48683D


Cycloparaphenylenes (CPPs) are a remarkable class of hoop-shaped conjugated macrocycles with inimitable properties. Herein we describe a divergent synthesis of [7]CPP and [8]CPP. Furthermore we present the first crystal structure of [7]CPP. Thus, we now have established the size-selective synthesis of [n]CPP (n = 7–16) in a uniformed cyclohexane-based method.

Related post

  1. Infinitene: A Helically Twisted …
  2. Synthesis and properties of all-…
  3. Palladium-Catalyzed C–H and C–N …
  4. Flexible Reaction Pocket on Bulk…
  5. New paradigms in molecular nanoc…
  6. Adamantane-annulated arenes
  7. Pd-Catalyzed Direct C–H Bond Fun…
  8. CH Alkenylation of Azoles with E…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP