Blog

Cycloparaphenylene-Based Ionic Donor–Acceptor Supramolecule: Isolation and Characterization of Li+@C60⊂[10]CPP

Hiroshi Ueno, Taishi Nishihara, Yasutomo Segawa, and Kenichiro Itami

Angew. Chem. Int. Ed. 2015, Early View, 10.1002/anie.201500544

The first cycloparaphenylene (CPP)-based ionic donor–acceptor supramolecule Li+@C60⊂[10]CPP⋅X− has been synthesized. X-ray
crystallography not only confirmed the molecular structure of Li+@C60⊂[10]CPP⋅X− but also uncovered the formation of a unique ionic crystal. The strong charge-transfer interaction between [10]CPP and Li+@C60, which was confirmed by electrochemical measurement and spectroscopic analyses, caused significant delocalization of the positive charge across the entire complex.

Related post

  1. Oxidative Homocoupling Reaction …
  2. Controlled Alcohol–Carbonyl Inte…
  3. Carbon Nanosheets by Morphology-…
  4. Chemical hijacking of auxin sign…
  5. Curved Oligophenylenes as Donors…
  6. Macrocyclization by Rh-Catalyzed…
  7. カーボンナノリング:最短のカーボンナノチューブ
  8. Synthesis of Highly Twisted, Non…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

This error message is only visible to WordPress admins

Error: API requests are being delayed. New posts will not be retrieved.

There may be an issue with the Instagram access token that you are using. Your server might also be unable to connect to Instagram at this time.

Error: API requests are being delayed for this account. New posts will not be retrieved.

There may be an issue with the Instagram access token that you are using. Your server might also be unable to connect to Instagram at this time.

Error: No posts found.

Make sure this account has posts available on instagram.com.

Click here to troubleshoot

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP