Blog

Cycloparaphenylene-Based Ionic Donor–Acceptor Supramolecule: Isolation and Characterization of Li+@C60⊂[10]CPP

Hiroshi Ueno, Taishi Nishihara, Yasutomo Segawa, and Kenichiro Itami

Angew. Chem. Int. Ed. 2015, Early View, 10.1002/anie.201500544

The first cycloparaphenylene (CPP)-based ionic donor–acceptor supramolecule Li+@C60⊂[10]CPP⋅X− has been synthesized. X-ray
crystallography not only confirmed the molecular structure of Li+@C60⊂[10]CPP⋅X− but also uncovered the formation of a unique ionic crystal. The strong charge-transfer interaction between [10]CPP and Li+@C60, which was confirmed by electrochemical measurement and spectroscopic analyses, caused significant delocalization of the positive charge across the entire complex.

Related post

  1. Synthesis of Thiophene-Based TAK…
  2. Dehydrogenative Synthesis of 2,2…
  3. Negatively Curved Warped Nanogra…
  4. 1,3,5-Triaryl 2-Pyridylidene: Ba…
  5. Recent Progress in Nickel-Cataly…
  6. Programmed Synthesis of Tetraary…
  7. Branch-Selective Allylic C–H Car…
  8. Photoredox‐Catalyzed Decarboxyla…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP