2020

[347] Double-helix supramolecular nanofibers assembled from negatively curved nanographenes
Kenta Kato, Kiyofumi Takaba, Saori Maki-Yonekura, Nobuhiko Mitoma, Yusuke Nakanishi, Taishi Nishihara, Taito Hatakeyama, Takuma Kawada, Yuh Hijikata, Jenny Pirillo, Lawrence T. Scott, Koji Yonekura, Yasutomo Segawa, Kenichiro Itami
ChemRxiv 2020, DOI: 10.26434/chemrxiv.13270607.v1
J. Am. Chem. Soc. 2021, 143, 5465-5469. DOI: 10.1021/jacs.1c00863
Selected as Cover. Highlighted in many media worldwidely.

[346] Development of potent inhibitors for strigolactone receptor DWARF 14
Masahiko Yoshimura, Sojung F. Kim, Ryosuke Takise, Shuhei Kusano, Sakuya Nakamura, Masanori Izumi, Akiko Yagi, Kenichiro Itami, Shinya Hagihara
Chem. Commun. 2020, 56, 14917–14919. DOI: 10.1039/d0cc01989e

[345] A theoretical study on the strain energy of helicene-containing carbon nanobelts
Kosuke Watanabe, Yasutomo Segawa,* and Kenichiro Itami*
Chem. Commun. 2020, 56, 15044–15047. DOI: 10.1039/D0CC06373H

[344] Small Molecules Modulating Mammalian Biological Clocks: Exciting New Opportunities for Synthetic Chemistry
Kazuma Amaike, Tsuyoshi Oshima, Nicola Stephanie Skoulding, Yoshifumi Toyama, Tsuyoshi Hirota, Kenichiro Itami
Chem, 2020, 6, 2186–2198. DOI: 10.1016/j.chempr.2020.08.011

[343] A N-terminally deleted form of the CK2a’ catalytic subunit is sufficient to support cell viability
Christian Borgo, Claudio D’Amore, Luca Cesaro, Kenichiro Itami, Tsuyoshi Hirota, Lorenzo A. Pinna, Mauro Salvi
Biochem. Biophys. Res. Commun. 2020, 531, 409–415. DOI: 10.1016/j.bbrc.2020.07.112

[342] Key ingredients for a successful academic research institute
Wolf B. Frommer, Kenichiro Itami
EMBO Reports, 2020, 21, e51398. DOI: 10.15252/embr.202051398

[341] Creation of negatively curved polyaromatics enabled by annulative coupling that forms an eight-membered ring
Satoshi Matsubara, Yoshito Koga, Yasutomo Segawa, Kei Murakami, Kenichiro Itami
Nature Catal. 2020, 3, 710–718. DOI: 10.1038/s41929-020-0487-0
Highlighted in newspapers

[340] Synthetic strategies of carbon nanobelts and related belt‐shaped polycyclic aromatic hydrocarbons
Kwan Yin Cheun, Yasutomo Segawa, Kenichiro Itami
Chem. Eur. J2020, 26,14791–14801. DOI: 10.1002/chem.202002316

[339] Annulative π-extension (APEX) reactions for precise synthesis of polycyclic aromatic compounds
Hideto Ito, Wataru Matsuoka, Yuuta Yano, Mari Shibata, Kenichiro Itami
J. Synth. Org. Chem. Jpn. 2020, 78, 671–682. DOI: 10.5059/yukigoseikyokaishi.78.671

[338] Recent advances in C-H activation for the synthesis of π-extended materials
Iain A. Stepek, Kenichiro Itami
ACS Mater. Lett. 2020, 2, 951–974. DOI:10.1021/acsmaterialslett.0c00206

[337] Molecular Nanocarbon Science: Present and Future
Kenichiro Itami, Takehisa Maekawa
Nano Lett. 2020, 20, 4718–4720. DOI: 10.1021/acs.nanolett.0c02143

[336] Synthesis of Cycloiptycenes from Carbon Nanobelt
Chem. Sci. 2020, 11, 6775–6779. DOI: 10.1039/D0SC02501A

[335] Effect of nanocarbon molecules on the Arabidopsis thaliana transcriptome
Norihito Nakamichi, Ayato Sato, Yusuke Aihara, Toshinori Kinoshita, Yasutomo Segawa, Kazuma Amaike, Kenichiro Itami
bioRxiv 2020, DOI: 10.1101/2020.05.22.110171

[334] A unique small molecule pair controls the plant circadian clock
Takahiro N Uehara, Saori Takao, Hiromi Matsuo, Ami N. Saito, Eisuke Ota, Azusa Ono, Kenichiro Itami, Toshinori Kinoshita, Junichiro Yamaguchi, Norihito Nakamichi
bioRxiv 2020, DOI: 10.1101/2020.05.25.113746

[333] σ-Bond Hydroboration of Cyclopropanes
Hiroki KondoShin MiyamuraKaoru MatsushitaHiroki KatoChisa KobayashiArifinKenichiro ItamiDaisuke YokogawaJunichiro Yamaguchi
J. Am. Chem. Soc. 2020, 142, 11306–11313. DOI: 10.1021/jacs.0c05213

[332] A Non-alternant Aromatic Belt: Methylene-bridged [6]Cycloparaphenylene Synthesized from Pillar[6]arene
Yuanming Li, Yasutomo Segawa, Akiko Yagi, Kenichiro Itami
ChemRxiv 2020, DOI: 10.26434/chemrxiv.12415166.v1
J. Am. Chem. Soc. 2020, 142, 12850–12856. DOI:10.1021/jacs.0c06007

[331] Synthesis of a Zigzag Carbon Nanobelt
Kwan Yin Cheung, Kosuke Watanabe, Yasutomo Segawa, Kenichiro Itami
ChemRxiv 2020, DOI: 10.26434/chemrxiv.12324353.v1
Nature Chemistry 2021, 13, 255–259. DOI:10.1038/ s41557-020-00627-5

[330] An Isoform-Selective Modulator of Cryptochrome 1 Regulates Circadian Rhythms in Mammals
Simon Miller, Yoshiki Aikawa, Akiko Sugiyama, Yoshiko Nagai, Aya Hara, Tsuyoshi Oshima, Kazuma Amaike, Steve A. Kay, Kenichiro Itami, Tsuyoshi Hirota
Cell Chem. Biol. 2020, 27, 1192–1198. DOI: 10.1016/j.chembiol.2020.05.008

[329] Isoform-selective regulation of mammalian cryptochromes
Simon Miller, You Lee Son, Yoshiki Aikawa, Eri Makino, Yoshiko Nagai, Ashutosh Srivastava, Tsuyoshi Oshima, Akiko Sugiyama, Aya Hara, Kazuhiro Abe, Kunio Hirata, Shinya Oishi, Shinya Hagihara, Ayato Sato, Florence Tama, Kenichiro Itami, Steve A. Kay, Megumi Hatori, Tsuyoshi Hirota
Nature Chem. Biol. 2020, 16, 676-685. DOI: 10.1038/s41589-020-0505-1
Highlighted in Nature Chem. Biol.

[328] Programmable Synthesis of Multiply Arylated Cubanes through C–H Metalation and Arylation
Ryo Okude, Genki Mori, Akiko Yagi, Kenichiro Itami
Chem. Sci. 2020, 11, 7672–7675. DOI:10.1039/D0SC01909G
Highlighted in ChemistryViews!

[327] Synthesis of Nitrogen‐Containing Polyaromatics by Aza‐Annulative π‐Extension of Unfunctionalized Aromatics
Kou P. Kawahara, Wataru Matsuoka, Hideto Ito, Kenichiro Itami
Angew. Chem. Int. Ed. 202059, 6383-6388. DOI: 10.1002/anie.201913394 【detail

[326] Synthesis of polybenzoacenes: Annulative dimerization of phenylene triflate by twofold C-H activation
Mizuho Uryu, Taito Hiraga, Yoshito Koga, Yutaro Saito, Kei Murakami, Kenichiro Itami
Angew. Chem. Int. Ed. 2020, 59, 6551-6554. DOI: 10.1002/ange.202001211
Selected as VIP paper. Selected as Cover of the journal. Highlighted in ChemistryViews.

[325] Six-fold C-H borylation of hexa-peri-hexabenzocoronene
Mai Nagase, Kenta Kato, Akiko Yagi, Yasutomo Segawa, Kenichiro Itami
Beilstein J. Org. Chem. 2020, 16, 391-397. DOI: 10.3762/bjoc.16.37
Thematic issue on “C-H functionalization for materials science”.

[324] Selective transformation of strychnine and 1,2-disubstituted benzenes by C-H borylation
Yutaro Saito, Kotono Yamanoue, Yasutomo Segawa, Kenichiro Itami
Chem 2020, 6, 985-993. DOI: 10.1016/j.chempr.2020.02.004

[323] Rapid access to kinase inhibitor pharmacophore by regioselective C-H arylation of thieno[2,3-d]pyrimidine
Shuya Yamada, Kaylin Nicole Flesch, Kei Murakami, Kenichiro Itami
Org. Lett., 2020, 22, 1547-1551. DOI: 10.1021/acs.orglett.0c00143

[322] Roles of base in the Pd-catalyzed annulative chlorophenylene dimerization
Li-Ping Xu, Brandon E. Haines, Manjaly J. Ajitha, Kei Murakami, Kenichiro Itami, Djamaladdin G. Musaev
ACS Catal., 2020, 10, 3059-3073. DOI: 10.1021/acscatal.9b05328

[321] Synthesis of nitrogen-containing polyaromatics by aza-annulative π-extension of unfunctionalized aromatics
Kou P. Kawahara, Wataru Matsuoka, Hideto Ito, Kenichiro Itami
Angew. Chem. Int. Ed., 2020, 59, 6383–6388. DOI: 10.1002/anie.201913394

[320] Synthesis of highly twisted, nonplanar aromatic macrocycles enabled by axially chiral 4,5-diphenylphenanthrene building block
Yuanming Li, Akiko Yagi, Kenichiro Itami
J. Am. Chem. Soc. 2020, 142, 3246-3253. DOI: 10.1021/jacs.9b13549

[319] Synthesis and structure of [9]cycloparaphenylene catenane: An all-benzene catenane consisting of small rings
Yasutomo Segawa, Motonobu Kuwayama, Kenichiro Itami
Org. Lett. 2020, 22, 1067-1070. DOI: 10.1021/acs.orglett.9b04599

[318] A quest for structurally uniform graphene nanoribbons: synthesis, properties, and applications
Yuuta Yano, Nobuhiko Mitoma, Hideto Ito, Kenichiro Itami
J. Org. Chem. 2020, 85, 4-33. DOI: 10.1021/acs.joc.9b02814
Special issue on Functional Organic Materials. Selected as a front cover of the issue.

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