Blog

Phenanthro[9,10-a]corannulene by one-step annulative π-extension of corannulene

Kenta Kato, Yasutomo Segawa, and Kenichiro Itami

Can. J. Chem. 2016, Just-in article, DOI: 10.1139/cjc-2016-0467

The one-step π-extension of corannulene was achieved using a palladium-catalyzed C-H coupling reaction. The X-ray crystal structure and photophysical properties of the thus formed phenanthro[9,10-a]corannulene (1) were investigated, and the structural properties of 1 were examined by density functional theory calculations. In contrast to dibenzo[g,p]chrysene, the most stable structure of 1 was a butterfly-shaped structure, resulting from the bowl-shaped distortion of the corannulene moiety.

Related post

  1. Decarbonylative Diaryl Ether Syn…
  2. Annulative π-Extension (APEX) of…
  3. Casein kinase 1 family regulates…
  4. Selective Introduction of Organi…
  5. Thiophene-Fused π-Systems from D…
  6. Late-Stage C-H Bond Arylation of…
  7. Programmed Synthesis of Tetraary…
  8. C-H Arylation of Phenanthrene wi…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP