Blog

Manganese-Catalyzed Intermolecular C–H/C–H Coupling of Carbonyls and Heteroarenes

Keika Hattori, Asraa Ziadi, Kenichiro Itami, and Junichiro Yamaguchi

Chem. Comm. 2014, Accepted Manuscript DOI:10.1039/C4CC01376J

 Mn is to be catalyst under NaIO4 oxidant

Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes has been developed. The presence of NaIO4 as an oxidant is crucial for the catalytic reaction.

These new, inexpensive reaction conditions allow the gramscale synthesis of α-heteroaryl carboxylic acids.

 

 

Related post

  1. Controlled Alcohol–Carbonyl Inte…
  2. Annulative π-Extension of Indole…
  3. Nickel-Catalyzed Aromatic C–H Fu…
  4. Dehydrogenative Synthesis of 2,2…
  5. A General Catalyst for the b-Sel…
  6. Pd- and Cu-catalyzed C–H arylati…
  7. Topological molecular nanocarbon…
  8. Synthesis of Open-Shell Ladder π…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP