Organic Chemistry Laboratory, Nagoya University

Name

JIAO Jiao (Nickname–JoJo)

E-mail

jiao.jiao@itbm.nagoya-u.ac.jp

Hobby

Travelling, Pop Music, Japanese

Education

B.Sc. 2003.9~2007.7 School of Chemistry and Materials Science, Shaanxi Normal University (chemistry)

M.Sc. 2007.9~2010.7 School of Chemistry and Materials Science, Shaanxi Normal University (organic chemistry)

D. Sc. 2010. 10~2013. 9 Graduate School of Nature Science and Technology, Okayama University (functional molecular chemistry), MEXT fellowship

Research Interest

organometallic chemistry, organic synthesis

Publications

(1)  PdEDTA Held in an Ionic Liquid Brush as a Highly Efficient and Reusable Catalyst for Suzuki Reaction in Water.  Junfa Wei,* Jiao Jiao, Jinjuan Feng, Jing Lv, Xiru Zhang, Xianying Shi, Zhanguo Chen. J. Org. Chem. 2009, 74, 6283–6286. (PDF) (Highlighted by Synfacts 2009, 11, 1294. PDF)

(2) A Facile and Practical Copper Powder-Catalyzed, Organic Solvent- and Ligand-Free Ullmann Amination of Aryl Halides.  Jiao Jiao, Xiru Zhang, Ninghui Chang, Jie Wang, Junfa Wei,* Xianying Shi, Zhanguo Chen. J. Org. Chem. 2011, 76, 1180–1183. (PDF)

(3) Highly Regio- and Stereoselective Synthesis of Multialkylated Olefins through Carbozirconation of Alkynylboronates and Sequential Negishi and Suzuki-Miyaura Coupling Reactions.  Yasushi Nishihara,* Yoshiaki Okada, Jiao Jiao, Masato Suetsugu, Ming-Tzu. Lan, Megumi Kinoshita, Masayuki Iwasaki, Kentaro Takagi. Angew. Chem. Int. Ed. 2011, 50, 8660–8664. (PDF)

(4) Alkynylboron Compounds in Organic Synthesis.  Jiao Jiao, Yasushi Nishihara.* J. Organomet. Chem. 2012, 721-722, 3–16. (PDF)

(5) Palladium-Free Synthesis of Unsymmetrical Diarylethynes by Cross-Coupling Reaction of Alkynylboronates with Aryl Iodides Catalyzed by CuCl.  Daisuke Ogawa, Jing Li, Masato Suetsugu, Jiao Jiao, Masayuki Iwasaki, and Yasushi Nishihara.* Tetrahedron Lett. 2013, 54, 518–521. (PDF)

(6) Synthesis of Multisubstituted Olefins through Regio- and Stereoselective Silylborylation of an Alkynylboronate/Chemoselective Cross-Coupling Sequences.  Jiao Jiao, Kiyohiko Nakajima, and Yasushi Nishihara. Org. Lett. 2013, 15, 3294–3297. (PDF) (Highlighted by Synfacts 2013, 9, 1104. (PDF)

(7) Selective Synthesis of Multisubstituted Olefins Utilizing gem- and vic- Diborylated Vinylsilanes Prepared by Silylborylation of an Alkynylboronate and Diborylation of Alkynylsilanes.  Jiao Jiao, Keita Hyodo, Hao Hu, Kiyohiko Nakajima, and Yasushi Nishihara. J. Org. Chem. 2014, 79, 285–295. (PDF)

(8) Catalytic Methods for Aromatic C-H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules. Jiao Jiao, Kei Murakami, Kenichiro Itami. ACS Catalysis 2016, 6, 610–633. (PDF)

(9) The AMOR Arabinogalactan Sugar Chain Induces Pollen-tube Competency to Respond to Ovular Guidance. Akane G. Mizukami, Rie Inatsugi, Jiao Jiao, Toshihisa Kotake, Keiko Kuwata, Kento Ootani, Satohiro Okuda, Subramanian Sankaranarayanan, Yoshikatsu Sato, Daisuke Maruyama, Hiroaki Iwai, Estelle Garenaux, Chihiro Sato, Ken Kitajima, Yoichi Tsumuraya, Hitoshi Mori, Junichiro Yamaguchi, Kenichiro Itami, Narie Sasaki, Tetsuya Higashiyama. Current Biology, 2016, 26, 1091. DOI: 10.1016/j.cub.2016.02.040 (PDF)

(10) Palladium-catalyzed C–H Arylation of Pyridines with Aryl TriflatesJiao Jiao, Kei Murakami, and Kenichiro Itami. Chem. Lett. 2016, 45, 529–531. DOI: 10.1246/cl.160133 (PDF)

Book

“Applied Cross-Coupling Reactions” Ed by Y. Nishihara

Chapter 4, Pharmaceuticals  Jiao Jiao, Y. Nishihara* Springer (2013)

Presentation

1) Jiao Jiao, Yoshiaki Okada, Masato Suetsugu, Ming-Tzu Lan, Megumi Kinoshita, Masayuki Iwasaki, Kentaro Takagi, and Yasushi Nishihara

  Highly Selective Synthesis of Multialkylated Olefins through Carbozirconation of Alkynylboronates and Sequential Negishi and Suzuki-Miyaura Couplings (poster)

  The 58th Symposium on Organometallic Chemistry 2011 (2011.9.7-9/Nagoya University, Higashiyama Campus, Nagoya, Japan)

2) Jiao Jiao, Masayuki Iwasaki, and Yasushi Nishihara

  Highly Selective Synthesis of Multisubstituted Olefins through Silaboration of Alkynylboronates and Sequential Cross-Couplings (oral)

  The 92nd CSJ Annual Meeting 2012 (2012.3.25-28/Keio University, Hiyoshi Campus, Yokohama, Japan)

3) Jiao Jiao, Masayuki Iwasaki, Kiyohiko Nakajima, and Yasushi Nishihara

  Highly Selective Synthesis of Multisubstituted Olefins through Silaboration of Alkynylboronates and Chemoselective Suzuki-Miyaura Couplings (oral)

  The 93rd CSJ Annual Meeting 2013 (2013.3.22-25/Ritsumeikan University, Biwako-Kusatsu Campus, Shiga, Japan)

4) Jiao Jiao, Keita Hyodo, Hao Hu, and Yasushi Nishihara

  Highly Selective Synthesis of Multi-substituted Olefins through Diborylation of Alkynylsilanes and Cross-Coupling Reaction Sequences (poster)

  The 60th Symposium on Organometallic Chemistry 2013 (2013.9.12-14/Gakushuin University, Mejiro Campus, Tokyo, Japan)

5) Jiao Jiao, Akane Mizukami, Toshihisa Kotake, Yoichi Tsumuraya, Junichiro Yamaguchi, Kenichiro Itami, Tetsuya Higashiyama

Synthesis and Activity of Key Molecules Activating Pollen-tube Guidance (poster)

The 4th International Conference on the MEXT Project of Integrated Research on Chemical Synthesis “Synthetic Approaches to New Chemical Functions” (2014.7.10-11/ Kyoto University, Uji Campus, Kyoto, Japan)

6) Yasushi Nishihara, Jiao Jiao, Keita Hyodo, Hao Hu

Highly Selective Synthesis of Multi-substituted Olefins through Diborylation of Alkynylsilanes and Cross-Coupling Reaction Sequences

The XXVI International Conference on Organometallic Chemistry (ICOMC 2014) (2014.7.13-18/Sapporo, Hokkaido, Japan)

Comment

Girls, be ambitious, too! (from Dr. Clark’s “Boys, be ambitious!” girls’ version)

大きな夢を持ち、追い続けよう！ (From Eiichi Negishi)

Work hard, play harder, dream even more!　(The slogan of Itami group)