Manganese-Catalyzed Intermolecular C–H/C–H Coupling of Carbonyls and Heteroarenes

Keika Hattori, Asraa Ziadi, Kenichiro Itami, and Junichiro Yamaguchi

Chem. Comm. 2014, Accepted Manuscript DOI:10.1039/C4CC01376J

 Mn is to be catalyst under NaIO4 oxidant

Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes has been developed. The presence of NaIO4 as an oxidant is crucial for the catalytic reaction.

These new, inexpensive reaction conditions allow the gramscale synthesis of α-heteroaryl carboxylic acids.



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