Blog

Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A

 

Kazuma Amaike, Kei Muto, Junichiro Yamaguchi, and Kenichiro Itami

J. Am. Chem. Soc. 2012, ASAP. DOI: 10.1021/ja306062c

 

A nickel-catalyzed decarbonylative C−H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of expensive metal catalysts or silver- or copper-based stoichiometric oxidants. We have successfully applied this new C−H arylation reaction to a convergent formal synthesis of muscoride A.

 

Related post

  1. Synthesis of Triarylpyridines in…
  2. Reversible modulation of circadi…
  3. Synthesis and Structural Feature…
  4. Photoredox‐Catalyzed Decarboxyla…
  5. Theoretical Elucidation of Poten…
  6. Six-fold C–H Borylation of Hexa-…
  7. C−H Bond Functionalization: Emer…
  8. Synthesis of Octaaryl Naphthalen…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

This error message is only visible to WordPress admins
This endpoint has been retired

Error: No posts found.

Make sure this account has posts available on instagram.com.

Click here to troubleshoot

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP