Blog

Catalytic C–H Imidation of Aromatic Cores of Functional Molecules: Ligand-Accelerated Cu Catalysis and Application to Materials- and Biology-Oriented Aromatics

Takahiro Kawakami, Kei Murakami, and Kenichiro Itami

J. Am. Chem. Soc. 2015, 137, Just accepted.  DOI: 10.1021/ja5130012.

Easy installation of nitrogen into arenes

Versatile imidation of aromatic C–H bonds was accomplished. In the presence of copper bromide and 6,6’-dimethyl-2,2’-bipyridyl, a range of aromatics, such as polycyclic aromatic hydrocarbons, aromatic bowls, porphyrins, heteroaromatics, and natural products, can be imidated by N-fluorobenzenesulfonimide. A dramatic ligand-accelerated copper catalysis and an interesting kinetic profile were uncovered.

Related post

  1. Structurally uniform and atomica…
  2. Helically Twisted Tetracene: Syn…
  3. Synthesis and Structure of a Pro…
  4. MEDCHEM NEWS 28-2 Merging synthe…
  5. Gold‐Catalyzed C−H Imidation of …
  6. Exploitation of an additional hy…
  7. Dissecting plant hormone signali…
  8. Synthesis of a zigzag carbon nan…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

This error message is only visible to WordPress admins
This endpoint has been retired

Error: No posts found.

Make sure this account has posts available on instagram.com.

Click here to troubleshoot

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP