Blog

Branch-Selective Allylic C–H Carboxylation of Terminal Alkenes by Pd/sox Catalyst

Hiroki Kondo, Feng Yu, Junichiro Yamaguchi, Guosheng Liu, and Kenichiro Itami

Org. Lett2014, ASAP. DOI: 10.1021/ol5019135

 

 A ligand-controlled branch-selective allylic C− H carboxylation through Pd catalysis is described. Thedeveloped catalytic system, which consists of Pd(OAc)2 ,sulfoxide−oxazoline (sox) as a ligand and benzoquinone as an oxidant, couples terminal alkenes and carboxylic acids to furnish the corresponding branched allylic esters with high regioselectivity.

Related post

  1. Polycyclic Arene Synthesis by An…
  2. Molecular Catalysis for Fulleren…
  3. Size-selective synthesis of [9]-…
  4. Oxidative C–H/C–H Coupling of Az…
  5. A grossly warped nanographene an…
  6. β-Selective C–H Arylation of Pyr…
  7. Programmable Synthesis of Multip…
  8. Synthesis of Octaaryl Naphthalen…

Twitter@Itami Lab

Itami Lab Facebook

Instagram@Itami Lab

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP