Blog

Creation of negatively curved polyaromatics enabled by annulative coupling that forms an eight-membered ring

“Creation of negatively curved polyaromatics enabled by annulative coupling that forms an eight-membered ring”
Satoshi Matsubara, Yoshito Koga, Yasutomo Segawa, Kei Murakami,* Kenichiro Itami* (†Equial contribution)
Nature Catalysis 2020. DOI: 10.1038/s41929-020-0487-0.

We have developed a new catalytic reaction for connecting benzene rings to create an eight-membered ring structure, and established a precise and practical method of synthesis for three-dimensional nanocarbons.

The key to this method is a new reaction using a palladium catalyst which enables the formation of the octagonal structure. In this reaction, polycyclic aromatic hydrocarbon substrates connect to construct the octagonal structure and enable successful three-dimensional nanocarbon molecule synthesis.

For details, please see Press release: ITbM Research Highlight

 

Related post

  1. Nicola Skoulding
  2. Development and Elucidation of t…
  3. Nickel-Catalyzed α-Arylation of …
  4. Synthesis and Racemization Proce…
  5. Thiophene-Fused π-Systems from D…
  6. A Modular and Size-Selective Syn…
  7. Catalytic C–H Imidation of Aroma…
  8. Synthesis of α-Fluoroimines by C…

最近の記事

Flickr@Itamilab

天池先輩からコーヒースープ伴夫妻からのお歳暮です!潤さん、宮村さん、ありがとうございます!!武藤さん、ビールありがとうございます!平賀大都わーいやなさん、あつしさん、ありがとうございます!!だいぶ前だけど、Stripes look #ootdHalloween lookラインを洗う時ですら格好良く。戸谷先生教育実習!imageけいしゅう、誕生日おめでとう!誕生日は英吉家!!3年生に名古屋ぼろ勝ちアピール中!!アリシア卒業おめでとう女子会!
PAGE TOP